High-Temperature Fuel Cells for Mobile and Stationary Applications

Development of SOFC System for Geothermic Oil and Gas Application

Geothermic Fuel Cells (GFC) are being developed to harness the thermal energy released by solid-oxide fuel cells to process the oil shale within a geological formation. This will result in the simultaneous generation of electricity and oil. The concept involves the placement of high- temperature solid-oxide fuel cells within oil-shale formations hundreds of meters below the earth’s surface to heat oil shale to processing temperatures (350°C) required to convert the kerogen within the oil shale into liquid oil. Fueled by natural gas, these fuel cells continuously generate valuable electricity while heating the oil shale, dramatically altering both the projected oil price and the environmental footprint. This approach is in contrast to ex-situ processing in which the oil shale is mined and retorted above ground, a process that is both costly and environmentally invasive. Diagram of geothermic fuel cells process Research thrust areas for this unique application are in experimental testing of GFC modules, modeling the cell-stack and balance-of- plant assembly in the subsurface application environment to assist in its successful design and development, and the development of a multi- objective design and dispatch optimization model of the GFC assembly for unconventional oil and gas production. The primary aims of the modeling effort were to (1) predict the stack electrochemical performance and (2) elucidate the thermal characteristics of the stack assembly during operation through modeling and simulation. Optimization results indicate that the GFC performance is better than current in situ upgrading technologies that rely on electricity supplied from the grid at generation-and- transmission efficiencies near 33%.

FUNDING: Independent Energy Partners(IEP)
COLLABORATORS: DELPHI and IEP

PUBLICATIONS

  1. G. Anyenya,·R.J. Braun, K. Lee, N.P. Sullivan, A.M. Newman, Design and Dispatch Optimization of a Solid-Oxide Fuel Cell Assembly for Unconventional Oil and Gas Production, Optimization & Engineering19:1037–1081, (2018).
  2. G.Anyenya, N.P. Sullivan, R.J. Braun, Modeling and Simulation of a Novel 4.5 kWe Multi-Stack Solid-Oxide Fuel Cell Prototype Assembly for Combined Heat and Power, Energy Conversion & Management140:247–259, (2017).
  3. G.Anyenya, B. Haun, M. Daubenspeck, R.J. Braun, N.P. Sullivan, Experimental Testing of a Novel kW-scale Multi-stack SOFC Assembly for CHP, ASME Journal of Electrochemical Energy Conversion & Storage13(4):041001, (2016).

Current Projects

Past Projects

Selected Publications in This Research Area

Design of Protonic Ceramic Fuel Cell Systems and Their Potential as a Distributed Power Generator with Electric Efficiencies Exceeding 70% (working paper)

A. Dubois, K. Ferguson, R.J. Braun

Journal of Power Sources, (2020)

Development of kW-Scale Protonic Ceramic Fuel Cells and Systems

R.J. Braun, A. Dubois, K. Ferguson, C. Duan, C. Karakaya, R.J. Kee, … A. Wood

ECS Transactions, 91(1):997–1008, (2019)

Steady-State and Dynamic Modeling of Intermediate-Temperature Protonic Ceramic Fuel Cells

K.J. Albrecht, A. Dubois, K. Ferguson, C. Duan, R.P. O’Hayre, R.J. Braun

Journal of The Electrochemical Society, 166(10):F687–F700, (2019)

Development of a Novel High Efficiency, Low Cost Hybrid SOFC/Internal Combustion Engine Power Generator

R.J. Braun, E. Reznicek, C. Cadigan, N.P. Sullivan, R. Danforth, T. Bandhauer, S. Garland, D. Olsen, B. Windom, B. Schaffer

ECS Transactions, 91(1):355–360, (2019)

Highly Durable, Coking and Sulfur Tolerant, Fuel-Flexible Protonic Ceramic Fuel Cell

C. Duan, S. Ricote, H. Zhu, N. Sullivan, C. Karakaya, R.J. Kee, R.J. Braun, R. O’Hayre

Nature557:217–222, (2018)

Design and Dispatch Optimization of a Solid-Oxide Fuel Cell Assembly for Unconventional Oil and Gas Production

G. Anyenya, R.J. Braun, K. Lee, N.P. Sullivan, A. M. Newman

Optimization & Engineering, 19:1037–1081, (2018)

Benchmarking the Expected Stack Manufacturing Cost of Next Generation, Intermediate-Temperature Protonic Ceramic Fuel Cells with Solid Oxide Fuel Cell Technology

A. Dubois, S. Ricote, R.J. Braun

Journal of Power Sources, 369:65–77, (2017)

Modeling and Simulation of a Novel 4.5 kWe Multi-Stack Solid-Oxide Fuel Cell Prototype Assembly for Combined Heat and Power

G.Anyenya, N.P. Sullivan, R.J. Braun

Energy Conversion & Management, 140:247–259, (2017)

Experimental Testing of a Novel Kilowatt-Scale Multistack Solid-Oxide Fuel Cell Assembly for Combined Heat and Power

G.Anyenya, B. Haun, M. Daubenspeck, R. J. Braun, N.P. Sullivan

ASME Journal of Electrochemical Energy Conversion & Storage, 13(4):041001, (2016)

Readily Processed Protonic Ceramic Fuel Cells with High Performance at Low Temperatures

C. Duan, J. Tong, M. Shang, S. Nikodemski, M. Sanders, S. Ricote, A. Almansoori, R. O'Hayre

Science, 349(6254):1321–1326, (2015)

Modeling Intermediate Temperature Protonic Ceramic Fuel Cells

K.J. Albrecht, C. Duan, R. O’Hayre, R.J. Braun

ECS Transactions, 68(1):3165–3175, (2015)

A Mixed-Integer Nonlinear Program for the Optimal Design and Dispatch of Distributed Generation Systems

K. Pruitt, A. Newman, S. Leyffer, R.J. Braun

Optimization and Engineering15:167–197, (2014)

Evaluating Shortfalls in Mixed-Integer Programming Approaches for the Optimal Design and Dispatch of Distributed Generation Systems

K. Pruitt, R.J. Braun, A. Newman

Applied Energy102:386–398, (2013)

Establishing Conditions for the Economic Viability of Fuel Cell-Based, Combined Heat and Power Distributed Generation Systems

K. Pruitt, R.J. Braun, A. Newman

Applied Energy, 111:904–920, (2013)

Application of SOFCs in Combined Heating, Cooling and Power Systems

R.J. Braun and P. Kazempoor

Chap. 12 in Solid Oxide Fuel Cells: From Materials to System Modeling, T.S. Zhao and M. Ni, editors, Energy and Environment Series No. 7, Royal Society of Chemistry, Cambridge, U.K. (2013)

View Other Research Areas:

MODELING AND SYSTEMS ANALYSIS OF ALTERNATIVE FUEL PRODUCTION AND UTILIZATION SYSTEMS

RENEWABLES AND GRID-ENERGY STORAGE SYSTEMS